Автор: Takamichi Iida, Roderick I. L. Guthrie Название: The Thermophysical Properties of Metallic Liquids: 2 vols Set Издательство: Oxford University Press Год: 2015 ISBN: 978-0198729839; 978-0198729846 Язык: English Формат: pdf Размер: 15,4 mb Страниц: 296+152
The first volume provides the basic matters needed for understanding the thermophysical properties of metallic liquids and for developing reliable models to accurately predict the thermophysical properties of almost all metallic elements in the liquid state, together with methods for quantitative assessment of models/equations. The authors also review the structure of metallic liquids, which is based on the theory of liquids, density, volume expansivity, thermodynamic properties (evaporation enthalpy, vapour pressure, heat capacity), sound velocity, surface tension, viscosity, diffusion, and electrical and thermal conductivities. Finally, the essential points of methods used for measuring these experimental data are presented.
Volume 2 considers the essential conditions for a model to be truly predictive. The authors use a statistical approach to rate the validity of the various predictive models that have been previously used for evaluating various thermophysical properties. On the basis of this assessment, the authors have predicted values for the thermophysical properties of elemental metallic liquids, which are lacking in experimental data. They believe their predicted values are at least as reliable, and sometimes more reliable than corresponding experimental values. According to the periodic law, the authors provide the periodic variations in values of some twelve physical quantities or thermophysical properties. This is based on the electron configuration in the outermost energy level of metallic elements. Finally, a large number of experimental data for the physical quantities and thermophysical properties of liquid metallic elements are compiled.
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